Fluoroplastics, Volume 1

by Sina Ebnesajjad

Published 1 January 2000
Today, a generational change is taking place in the fluoropolymer industry. The pioneers of PTFE developed an astonishing mass of basic and applied technical work. Now many of these experts are retiring and a new generation is taking their place. This new generation brings a plethora of skills, built upon the basic knowledge of fluoropolymer technology.

Speaking to the needs of today's engineering and science students and practicing professionals, this book provides an in-depth treatment of homofluoropolymer polymerization and part fabrication technology. A comprehensive range of issues surrounding the manufacturing of the monomer; polymer, fabrication, end-use, safety, and disposal are covered. The book has been arranged to allow self-managed reading and learning. It is both a source of data and a reference.

In this first book on an additive group of growing importance, the authors review the commercial additives available on the market. The applications chapters provide you with a step by step description of techniques to select and incorporate these additives in various products.

Engineers and scientits involved in polymer processing need practical information about these additives, their applications, and proper and safe handling. Until now much of this information has been difficult to obtain because of commercial secrecy.

In recent years, the applications of fluoropolymer additives have expanded significantly, with even the meaning of 'fluoropolymer additives' expanding from relatively the narrow definition of PTFE powder fillers to a wide variety of fluoropolymer elastomers, used as a processing aid for plastics processing such as extrusion, injection molding, and film blowing. The benefits of fluoropolymer additives used in plastics are the elimination of sharkskin defects, increases in process speed and output (up to 20%), the reduction of die build up, the reduction of gels and optical defects, etc.

In addition, fluropolymer additives are being increasingly used in inks, lubricants, and coatings. For example, in the coating industry fluoropolymer additives can increase the life cycle of exterior coatings due to their excellent weatherability and subsequently increase the time between recoats.

Following the successful first, the second edition is a complete guide to all that is required to successfully bond materials. It is both a reference and a source for learning the basics for those involved in the entire product value chains. Basic principles of adhesion such as surface characterization, types of adhesive bonds, and adhesion failure topics are covered in addition to a description of common adhesive materials and application techniques.

This is the second of a two volume series of books about fluoroplastics. Volume 1 covers the non-melt processible homopolymers, requiring non-traditional processing techniques. Volume 2 is devoted to the melt-processible fluoropolymers, their polymerization and fabrication techniques including injection molding, wire, tube, and film extrusion, rotational molding, blow molding, compression molding, and transfer molding. Both a source of data and a reference, the properties, characteristics, applications, safety, disposal, and recycling of melt-processible fluoropolymers are comprehensively detailed for immediate use by today's practicing engineering and scientists in the plastics industry. Students will benefit from the book's arrangement and extensive references.

Polyvinyl Fluoride

by Sina Ebnesajjad

Published 1 January 2012
The commercial PVF film Tedlar (R) was first trademarked by DuPont 50 years ago. Since that time it has established itself as a polymer with excellent resistance to sunlight degradation (UV resistance), thermal stability, chemical attack, water absorption, and solvents. These properties, together with a high solar energy transmittance rate, have led to it becoming established worldwide as the number one choice for the backsheets of photovoltaic solar panels, and a fire-retardent coating used in aircraft.

This book is the first and only handbook that describes polyvinyl fluoride preparation, technology, processing, fabrication and applications - making it essential reading for engineers and scientists working in industry sectors where PVF is utilized.

Handbook of Adhesives and Surface Preparation provides a thoroughly practical survey of all aspects of adhesives technology from selection and surface preparation to industrial applications and health and environmental factors. The resulting handbook is a hard-working reference for a wide range of engineers and technicians working in the adhesives industry and a variety of industry sectors that make considerable use of adhesives. Particular attention is given to adhesives applications in the automotive, aerospace, medical, dental and electronics sectors.

Introduction to Fluoropolymers demystifies fluoropolymers for a wide audience of designers, engineers, sales staff and managers. This important group of high-performance polymers has applications across a wide range of market sectors, including automotive, aerospace, medical devices, high performance apparel, oil & gas, renewable energy / solar photovoltaics, electronics / semiconductor, pharmaceuticals, and chemical processing.

Dr. Ebnesajjad covers the history and applications of a wide variety of materials, including expanded polytetrafluoroethylene, polyvinyl fluoride, vinylidene fluoride polymers and fluoroelastomers, just to name a few. Properties and applications are illustrated by real-world examples as diverse as waterproof clothing, vascular grafts and coatings for aircraft interiors. The different applications of fluoropolymers show the benefits of a group of materials that are highly water-repellant and flame-retardant, with unrivalled lubrication properties and a high level of biocompatibility. Health and safety and environmental aspects are also covered throughout the book.

Expanded PTFE Applications Handbook: Technology, Manufacturing and Applications is a comprehensive guide to ePTFE, explaining manufacturing technologies, properties, and applications. Technologies that were previously shrouded in secrecy are revealed in detail, as are the origins and history of ePFTE.

The book is an essential handbook for scientists and engineers working in PTFE processing industries, and for manufacturers working with fluoropolymers. It is also of use to purchasing managers and academics.

Fluoropolymers in the 21st Century is a concise but complete tutorial on these high performance materials from manufacturing to disposal, with a particularly emphasis on sustainability. The book considers three primary factors which are having an impact on the industry: environmental concerns and the need for improved sustainability, globalization of manufacturing and consumption, and the transition of legacy companies out of traditional materials and into the life sciences.

With the fate of the industry uncertain, the book traces the trends developed through the early decades of the material through to the present day and beyond, providing a thorough introduction to new practitioners in this field, and presenting key expert insights into the future direction in fluoropolymer technologies and products.

By putting together this information and insight into a single volume, this book provides materials scientists, chemical engineers, polymer scientists and engineers working in a range of industries - such as automotive, aerospace, power generation, and chemical processing - with an introduction to fluoropolymer materials and current trends in their use, as well as indicating future directions for research and application in this field.

Handbook of Thermoplastic Fluoropolymers gathers key technical information about structure, characteristics, properties and processing methods of commercial thermoplastic fluoropolymers in one easy reference. Thermoplastic fluoropolymers have many desirable functional characteristics, such as high thermal stability, reliability at high mechanical loads, a wide range of operating temperatures, and high chemical and radiation stability. These characteristics make them crucial in many specialist applications, including in the military, biopharmaceuticals and environmental protection. This uniquely comprehensive guide to this versatile family of polymers will help processors, fabricators and end-users find new and innovative solutions.

Detailed coverage of technical details of processing methods, characteristics, and chemical properties of commercial thermoplastic fluoropolymers all in one place make this the most authoritative reference to the subject available.