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Molecular manipulation of nano- and microstructures paves the way to produce organic polymer materials by design. Such architectures comprise both the synthesis and the kinetics and thermodynamics of macromolecular organization and is the theme of this volume. The book consists of four articles reviewing living polymerization to produce precisely defined linear polyesters, comparing them to other living polymerization techniques. The articles also deal with the synthesis of polymeric dendrimers,...

This is the first book on non-equilibrium thermodynamics. It covers a gap that has been left by the treatment of separation processes using classical thermodynamics. Because separation phenomena are dynamic processes, classical thermodynamics may not describe the true phenomena occurring in a particular separation media; rather a flux of entropy will bring the system out of the classical equilibrium and, as a consequence, different rules should apply – non-equilibrium thermodynamics. This book o...

Amidst developments in nanotechnology and successes in catalytic emulsion polymerization of olefins, polymerization in dispersed media is arousing an increasing interest from both practical and fundamental points of view. This text describes ultramodern approaches to synthesis, preparation, characterization, and functionalization of latexes, nanopa

This book presents the state-of-the-art in modelling and simulation on supercomputers. Leading German researchers present results achieved on systems of the High Performance Computing Center Stuttgart (HLRS) for the year 2005. The reports cover all fields of computational science and engineering, ranging from CFD via computational physics and chemistry to computer science. Special emphasis is given to industrially relevant applications. Presenting results for both vector-systems and micro-proces...

This book provides a concise, approachable description of how modern NMR experiments work, aimed principally at those who use, or might use, an NMR spectrometer and are curious about why the spectra look the way they do. It provides, in an accessible and relatively informal fashion, the conceptual and theoretical tools needed to understand the inner workings of some of the most important multi-pulse, multi-nuclear, multi-dimensional techniques that chemists and biochemists use to probe the struc...

This work summarises recent results in the rapidly developing discipline of the computational aspects of biochemical reactivity. It presents a comprehensive and critical treatise on the subject, with numerous references covering all relevant and recent work. The chapters, written by experts in the field, deal with quantum mechanical models for reactions in solution, ab initio molecular orbital studies on enzymatic reactions, combined quantum-classical models for proteins, force field approaches...

The major reason forpresentingabiblio­ ultraviolet light, or which make only a casual graphy on fluorescence and phosphorescence reference to the fluorescence technique were can be summed up in one statement: A recent usually rejected. However, occasionally survey showed that twenty-two percent of all papers of this nature were included because chemical and clinical research was uninten­ fluorescence methods seem to have unusual tionally duplicated. A comprehensive source potential for the probl...

The combination of spectroscopy and theory has developed considerably in the past two decades. Computational techniques and theoretical analysis to extract electronic structure information from spectroscopy has become a crucial aspect of modern research in chemistry and materials science. This book provides a comprehensive and up-to-date resource on spectroscopic methods used in transition metal chemistry and explains the relationships between experimental techniques and electronic structure....

Our understanding of carbene chemistry has advanced dramatically, especially in the last decade, and new developments continue to emerge. Some of the recent exciting findings have been collected in the first and second volumes of Advances in Carbene Chemistry. With the third volume, the series continues to provide a periodic coverage of carbene chemistry in its broadest sense. Beginning as chemical curiosities, carbenes are now solidly established as reactive intermediates with fascinating and...

This book provides a definitive account of our present understanding of the forces between molecules. It deals with both the origins of such forces and their quantitative determination using a combination of theoretical and experimental techniques. The book brings together detailed treatments of both the traditional approaches which relate the bulk properties of matter to the intermolecular potential and more recently developed methods based upon scattering and spectroscopic techniques. The topi...

Dieser Buchtitel ist Teil des Digitalisierungsprojekts Springer Book Archives mit Publikationen, die seit den Anfängen des Verlags von 1842 erschienen sind. Der Verlag stellt mit diesem Archiv Quellen für die historische wie auch die disziplingeschichtliche Forschung zur Verfügung, die jeweils im historischen Kontext betrachtet werden müssen. Dieser Titel erschien in der Zeit vor 1945 und wird daher in seiner zeittypischen politisch-ideologischen Ausrichtung vom Verlag nicht beworben.

This book considers the various advanced hydrogen materials and technologies of their synthesis. It presents the consideration of the physics, chemistry, thermodynamics and kinetics of processes of energy conversion, which occur at hydrogen production, storage, transportation and with its use. It also discusses the pioneering attempts to transform motor transport, airplanes, domestic technics, illumination and industrial manufacture of hydrogen fuel.