This volume, part 3 of the third supplement, continues the updating of the previous volumes on boron compounds: "Boron Compounds" Vols. 1 - 20, "Boron" 1st Suppl. Vol. 1 - 3 (1980/81), "Boron" 2nd Suppl. vols. 1 + 2 (1980/83). This volume deals with the compounds of boron with nitrogen and of boron with fluorine. The modifications of boron nitride are now important materials in modern technology. They have many applications, e.g. as fibers or coatings, in ceramics or alloys, as fillers in organic polymers, for machining of metals and as solid lubricants. They are used in the preparation of semiconductors and in laser nuclear technology. In the chapter on L-triorganyl-N-triorganylborazines, (-Br-Nr-)3, the compound (-B(i-C3H7)-N(t-C4H9)-)3 is the first species having a Dewar-borazine structure, which contains a 1,4 bond and two parallel double bonds in the 6-ring system. Trifluoroborane, BF3, and also its adduct with ether, is important especially in catalytic applications. Among tetra-fluoroborates ANOU ABF4U, ANO2U ABF4U and ANF4U ABF4U are also described. The systems with C1, Br and J with chalcogenes, and finally the carboranes, are contained in the final 4th volume of this series. Volume 4 will also include a formula index for volumes 1 to 4."
- ISBN10 3540935576
- ISBN13 9783540935575
- Publish Date 24 November 1987
- Publish Status Active
- Out of Print 11 November 2010
- Publish Country DE
- Publisher Springer-Verlag Berlin and Heidelberg GmbH & Co. KG
- Imprint Springer-Verlag Berlin and Heidelberg GmbH & Co. K
- Edition 8th ed.
- Format Hardcover
- Pages 398
- Language English